The XYZ system will give you the data you need. There are some things about it I don't like as a power user, but for the job of improving the speaker/room interface, it'll do what you want. Having data is one thing however, interpreting it is another. Once you start collecting data, post screen shots and we'll help you figure out what to make of it.
If I remember the picture of your room, you had a lot of left/right asymmetry where the right side was close to 2 wall boundaries. My guess would be the majority of your problems are coming from that side, bass boost from boundary gain, and short window reflections that hurt imaging cues. My suggestion is to collect some baseline data first for both left and right side individually, and both speakers together, gated and ungated FR (taken both at 1m and your listening position), and various forms of decay times. Then apply some treatments to the right side problem area, bass trapping in the corner and first reflection point absorption, then take the same measurements again and compare.